期刊
ORGANIC LETTERS
卷 12, 期 6, 页码 1200-1203出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol902970z
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资金
- Welch Foundation [E-1571]
- NIGMS [R01GM077635]
- A. P. Sloan Foundation
- Camille and Henry Dreyfus Foundation
- Norman Hackerman Advanced Research Program
A number of first-row transition metal salts catalyze deprotonative dimerization of acidic arenes. Under the atmosphere of oxygen, nickel, manganese, cobalt, and Iron chlorides have been shown to dimerize five- and six-membered ring heterocycles as well as electron-poor arenes. Both tetramethylpiperidide and dicyclohexylamide bases can be employed; however, the former afford slightly higher yields.
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