期刊
ORGANIC LETTERS
卷 12, 期 3, 页码 440-443出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol9025765
关键词
-
资金
- National Institutes of Health [GM57873]
The mono-triflate salts of some chiral nonracemic 1,2-diamines react with alpha-ketoenones in a stoichiometric reaction to form products of the Nazarov cyclization in high enantiomeric ratios. The mechanism appears to involve rearrangement of an enamine-iminium ion.
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