期刊
ORGANIC LETTERS
卷 12, 期 17, 页码 3804-3807出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol101498r
关键词
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资金
- Japan Society for the Promotion of Science (JSPS)
- Ministry of Education, Culture, Sports, Science and Technology (MEXT)
- Ritsumeikan Global Innovation Research Organization (R-GIRO)
- New Energy and Industrial Technology Development Organization (NEDO) of Japan
A new synthetic concept for obtaining unsymmetrical biaryl coupling products by an oxidative method is reported. Our synthetic strategy casts light on the reaction intermediate for switching the reactivity of 3-substituted thiophenes. On the basis of this strategy, a novel direct method for the synthesis of head-to-tail bithiophenes using hypervalent iodine(III) reagents has been developed.
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