期刊
ORGANIC LETTERS
卷 12, 期 15, 页码 3544-3547出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol101393h
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资金
- EPSRC [EP/F028806/01]
- EPSRC Mass Spectrometry Service (Swansea)
- Engineering and Physical Sciences Research Council [EP/H025952/1] Funding Source: researchfish
- EPSRC [EP/H025952/1] Funding Source: UKRI
A cyclic porphyrin trimer has been synthesized which has a high affinity for fullerenes. It forms 1:1 complexes with C-60 and C-70 with association constants of 2 x 10(6) and 2 x 10(8) M-1, respectively, in toluene. Its affinities for C-86 and La@C-82 are too strong to measure by fluorescence titration. The solvent dependence of the association constants shows that solvation of both the guest and the host influence the binding strength.
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