期刊
ORGANIC LETTERS
卷 12, 期 6, 页码 1280-1283出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol100169r
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资金
- National Natural Science Foundation of China [20732003, 20872097]
- PC-SIRT [IRT0846]
- Major State Basic Research and Development Program [2010CB833300]
Asymmetric cyanation of a class of easily available olefins with a favorable cyanide source ethyl cyanoformate (CNCOOEt) was realized by an interesting modular catalyst. High yields and ee values were obtained for a range of substrates under solvent-free and mild reaction conditions. The products obtained could be easily transformed to the enantioenriched useful intermediates 5, 6, and pharmaceutically important gamma-aminobutyric acid 7.
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