期刊
ORGANIC LETTERS
卷 12, 期 9, 页码 2112-2115出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol100604m
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资金
- NIH [CA 53604]
Enantioenriched homoallylic ethers containing a alpha,beta-unsaturated ester (syn-vinylogous aldol products) were directly accessed by Lewis acid catalyzed crotylation utilizing chiral silane 2. The reagents were prepared by enantioselective Si-H Insertion to an alpha-diazovinylacetates using Davies' Rh-2(DOSP)(4) catalyst or chiral Cu(I) Schiff base complex.
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