期刊
ORGANIC LETTERS
卷 12, 期 20, 页码 4644-4647出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol101993q
关键词
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资金
- National Science Foundation [CHE-1009038]
- Government of Russia [FCP GK 02 740 11 5211, Zayavka 2010-1 5-000-010-044]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1009038] Funding Source: National Science Foundation
Alkylcarboxamides can be converted to the respective amines by Hofmann rearrangement using hypervalent iodine species generated in situ from Phl and Oxone in aqueous acetonitrile On the basis of this reaction, a convenient experimental procedure for the preparation of alkylcarbamates using Oxone as the oxidant in the presence of iodobenzene in methanol has been developed. An efficient method for direct conversion of substituted benzamides to the respective quinone derivatives by treatment with Oxone and iodobenzene in aqueous acetonitrile has also been found
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