期刊
ORGANIC LETTERS
卷 12, 期 6, 页码 1180-1183出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol902921s
关键词
-
资金
- National Institutes of Health [GM079593, GM070620]
- Kansas University NIH Center of Excellence in Chemical Methodology and Library Development [P50 GM069663]
A variety of substituted benzisoxazoles has been prepared by the [3 + 2] cycloaddition of nitrile oxides and arynes. Both components, being highly reactive Intermediates, have been generated In situ by fluoride anion from readily prepared aryne precursors and chlorooximes. The reaction scope is quite general, affording a novel, direct route to functionalized benzisoxazoles under mild reaction conditions.
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