期刊
ORGANIC LETTERS
卷 12, 期 22, 页码 5234-5237出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol1022728
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资金
- Duke University
- NCBC [2008-1DG-1010]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0923097] Funding Source: National Science Foundation
A broadly applicable asymmetric synthetic strategy utilizing N-amino cyclic carbamate alkylation that provides access to the various stereochemical permutations of a common structural motif found in many polycyclic polyprenylated acylphloroglucinols is described. The utility of this methodology is demonstrated through the first asymmetric total synthesis of the antiviral agent (+)-clusianone.
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