期刊
ORGANIC LETTERS
卷 12, 期 23, 页码 5402-5405出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol102181r
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资金
- Ministry of Education in Singapore [ARC12/07, T206B3225]
- Nanyang Technological University (URC) [RG53/07]
The catalytic asymmetric synthesis of densely functionalized cis-isoxazoline N-oxides was realized with novel use of an organocatalyst, (S)-2-(azidodiphenylmethyl)pyrrolidine (4e) (Tan, B.; Zhu, D.; Zhang, L.; Chua, P. J.; Zeng, X.; Zhong, G. Chem.-Eur. J. 2010, 16, 3842; Olivares-Romero, J. L.; Juaristi, E. Tetrahedron 2008, 64, 9992), via an elegant formal [4 + 1] annulation strategy using readily available 2-nitroacrylates and alpha-iodoaldehydes.
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