期刊
ORGANIC LETTERS
卷 12, 期 8, 页码 1660-1663出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol100093u
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资金
- Deutsche Forschungsgemeinschaft
- Bayer-Schering
- Pharma AG
- Bayer Services GmbH
- BASF AG
- Sasol GmbH
A highly, stereo- and regioselective Meerwein - Ponndorf - Verley - Aldol etherification process of enolizable aldehydes is described. This new transformation is catalyzed by trifluoroacetic acid. The method also allows cross-aldol reactions with alpha-branched enolizable aldehydes and thus provides access to defined configured quaternary stereogenic centers.
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