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卷 12, 期 8, 页码 1696-1699出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol100220c
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资金
- National Natural Science Foundation of China [20702058, 20872157]
- Chinese Academy of Sciences [08QA14079]
- Shanghai Institute of Organic Chemistry
With the cooperation of Cram's phenonium ion, a novel cascade reaction was illustrated to construct pyrrolo[1,2-a]quinolines as a sole diastereoisomer in good to excellent yields. Preliminary mechanistic studies revealed that the gamma-lactam ring and electron-rich arene are important driving forces for ring contraction.
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