期刊
ORGANIC LETTERS
卷 12, 期 2, 页码 252-255出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol902565s
关键词
-
资金
- National Natural Science Foundation [30630072, 30721005]
- Chinese Academy of Sciences [SIMM0709QN-06]
- Third World Academy of Sciences
Grandifotane A (1), a limonoid with an unprecedented carbon skeleton, was isolated from the stem bark of Khaya grandifoliola. The structure of 1 with the absolute configuration was determined by spectroscopic data, X-ray crystallography, and ECD calculation. A biogenetic route for grandifotane A (1) Involving an enzymatic Baeyer-Villiger oxidation as the key step Is proposed.
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