期刊
ORGANIC LETTERS
卷 12, 期 2, 页码 376-379出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol902451h
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资金
- NSERC
- Inorganic Chemistry Exchange (ICE)
B(C6F5)(3)-catalyzed bis(hydrosilylation) of alpha-diketones can give high diastereomeric excess of either meso/anti (small silanes and disilane reagents) or dl/syn (bulky silanes) silyl-protected 1,2-diols. This easily tuned diastereoselectivity is rationalized based on the classic Felkin-Anh model applied to a mechanism relying on Si-H abstraction by the electrophilic borane reagent.
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