期刊
ORGANIC LETTERS
卷 12, 期 16, 页码 3610-3613出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol101319f
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资金
- National Science Council of Republic of China [NSC 96-2113-M-007-020-MY3]
A highly regio- and stereoselective nickel-catalyzed three-component coupling of alkynes with enones and alkenyl boronic acids to afford highly substituted 1,3-dienes is described. The reaction can also be extended to cyclization of enynes with coupling to alkenyl boronic acids. A possible reaction mechanism involving a five-membered nickelacycle as a key intermediate is proposed.
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