期刊
ORGANIC LETTERS
卷 12, 期 24, 页码 5612-5615出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol102221x
关键词
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资金
- National Natural Science Foundation of China [20872149]
- Chinese Academy of Sciences
By mimicking the scaffolds of oligopyridine-based ligands, triurea and tetraurea receptors have been developed for sulfate binding. The triureas (L-1, L-2) show stronger binding of sulfate than tetraureas (L-3, L-4) in DMSO because of their better conformational complementarity with sulfate, while the tetraureas display better water tolerance benefiting from the chelate effect and hydrophobic effect.
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