期刊
ORGANIC LETTERS
卷 12, 期 4, 页码 704-707出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol9026683
关键词
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资金
- Natural Sciences and Engineering Research Council (NSERC) of Canada
- Canadian Foundation for Innovation (CFI)
- Memorial University of Newfoundland
An acetylenic phenyldithiafulvene was developed as a versatile synthon for diverse TTFV-based macromolecular scaffolds. Through different coupling reaction sequences, shape-persistent macrocycles and linear TTFV-embedded polymers have been obtained and thereafter characterized by spectroscopic and voltammetric analyses. The TTFV polymer thin films generated via electropolymerization of a dithiafulvenyl-end-capped diyne monomer showed promising prospects in electrochromic and redox switchable molecular devices.
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