期刊
ORGANIC LETTERS
卷 12, 期 13, 页码 2990-2993出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol101007n
关键词
-
资金
- NIH [AI-42010]
- Bristol-Myers Squibb
- University of Pennsylvania
To expand the potential conformational space available to the polypyrroline structural motif, an open chain, D,L-alternating hexapyrrolinone was designed and synthesized. Structural studies, including solution NMR and X-ray crystallographic analysis, revealed that the hexapyrrolinone adopts a turn conformation both in solution and in the solid state, with aggregation in solution and a nanotube-like quaternary structure in the crystal.
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