期刊
ORGANIC LETTERS
卷 11, 期 13, 页码 2852-2854出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol9010739
关键词
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资金
- Swedish Research Council
Palladium pincer complexes directly catalyze the redox coupling reactions of functionalized alkenes and iodonium salts. The catalytic process, which Is suitable for mild catalytic functionalization of allylic acetates and electron-rich alkenes, probably occurs through Pd(IV) intermediates. Due to the strong metal-ligand interactions, the oxidation of phosphine and amine ligands of the pincer complexes can be avoided in the presented reactions.
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