期刊
ORGANIC LETTERS
卷 11, 期 17, 页码 3998-4000出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol901642w
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资金
- University of Minnesota
- Department of Chemistry
Regioselective cyclizations of alkyne-tethered cyclohexadienones can be accomplished under palladium catalysis. The cyclization involves an Initial Pd-mediated acetoxylation of the alkyne, followed by migratory insertion and protonolysis of the resulting palladium enolate. The predictable regloselectivity of these atom-economical and stereoselective reactions is influenced by developing steric interactions during migratory insertion of a vinyl palladium intermediate.
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