期刊
ORGANIC LETTERS
卷 11, 期 10, 页码 2177-2180出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol900461v
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资金
- NSFC [20525206, 20772052, 90813012, 20621091]
An enantioselective Friedel-Crafts alkylation of 4,7-dihydroindoles and alpha,beta-unsaturated alclehydes has been developed. The process is promoted by diphenylprolinol ether to afford 2-substituted 4,7-dihydroindoles in high yields and enantioselectivities. After a subsequent oxidation of the products, the optically active 2-substituted indoles could be obtained smoothly in high yields without any loss of enantioselectivity.
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