期刊
ORGANIC LETTERS
卷 11, 期 10, 页码 2145-2147出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol9007712
关键词
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资金
- Ministry of Education, Culture, Sports, Science and Technology, Government of Japan
- Grants-in-Aid for Scientific Research [21350020] Funding Source: KAKEN
The Cu-Xantphos system [Cu(O-t-Bu)-Xantphos, 10-15 mol %] catalyzes the intramolecular hydroamination of unactivated terminal alkenes bearing an unprotected aminoalkyl substituent in alcoholic solvents, giving pyrrolidine and piperidine derivatives in excellent yields. This system is applicable to both primary and secondary amines and tolerates a variety of functional groups.
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