期刊
ORGANIC LETTERS
卷 11, 期 5, 页码 1063-1066出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol8028127
关键词
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资金
- Israel Science Foundation
- German-Israeli Project Cooperation (DIP)
- Institute of Catalysis Science and Technology, C, Technion
- Skaggs Institute for Chemical Biology
A variety of functionalized penta-arylcorannuiene derivatives were prepared In high yields and high chemoselectivity by a cross-coupling reaction between sym-pentachlorocorannuiene and substituted arylboronic acids using Fu's Pd(0) catalyst. This approach provides a general entry to penta-substituted corannulene derivatives, which are useful building blocks for various structures of high complexity, such as pentagonal dendrimers, synthetic capsids, and discotic liquid crystals. This was demonstrated here by the facile synthesis of a third generation pentagonal dendrimer.
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