期刊
ORGANIC LETTERS
卷 11, 期 5, 页码 1075-1078出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol802860u
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资金
- University of South Florida
- New Researcher Award
- Petroleum Research Fund (PRF) [45899-G1]
- National Institutes of Health (NIH) [GM-082935]
A highly enantioselective hydrogenation of enamides catalyzed by a dual chiral-achiral acid system was developed. By employing a substoichiometric amount of a chiral phosphoric acid and acetic acid, catalyst loadings as low as 1 mol % of the chiral catalyst were sufficient to provide excellent yield and enantioselectivity of the reduction product.
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