期刊
ORGANIC LETTERS
卷 11, 期 23, 页码 5514-5517出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol902335c
关键词
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资金
- Spanish Ministerio de Ciencia c Innovacion [CTQ2006-01121, CTQ2009-07791]
- UAM-Consejeria de Educacion de la Comunidad Autonoma de Madrid [CCG08-UAM/PPQ-4454]
- Comunidad Autonoma de Madrid
A mild palladium-catalyzed Kumada-Corriu reaction of secondary benzylic bromides with aryl and alkenyl Grignard reagents has been developed. In the presence of the Xantphos ligand, the undesired beta-elimination pathway is minimized, affording the corresponding cross-coupling products in acceptable to good yields. The reaction proceeds with inversion of the configuration.
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