期刊
ORGANIC LETTERS
卷 11, 期 9, 页码 1927-1930出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol900330p
关键词
-
资金
- Ministry of Education in Singapore [ARC12/07, T206B3225]
- Naryang Technological University [RG140/06]
A remarkable organocatalyst that facilitates the asymmetric Michael addition of cyclic ketones to nitroolefins in excellent stereoselectivities (98:2 to >99:1 dr, 92% to >99% ee) has been developed and afforded various types of optically active nitroalkane derivatives of synthetic and biological importance. The extremely simple and practical operational procedure at room temperature increases the attractiveness of this reaction.
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