期刊
ORGANIC LETTERS
卷 11, 期 7, 页码 1607-1610出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol900298e
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资金
- Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan
C-H, N-H Coupling of azoles takes place with several amines in the presence of a copper catalyst to undergo amination at the 2-position. The reaction of benzothiazole with N-methylaniline in the presence of sodium acetate and 20 mol % Cu(OAc)(2) in xylene under an oxygen atmosphere afforded the aminated product in 81% yield.
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