期刊
ORGANIC LETTERS
卷 11, 期 14, 页码 3040-3043出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol901044m
关键词
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资金
- FWO (Fund for Scientific Research - Flanders)
- KU Leuven
- Ministerie voor Wetenschapsbeleid
A novel family of homoselenacalix[n]arenes (n = 3-8), with bridging CH2SeCH2 groups connecting the aryl subunits, has been synthesized via two different approaches employing nucleophilic Se species. The macrocycles are adequately characterized, including single-crystal X-ray structures for the homoselenacalix[4]- and homoselenacalix[6]arene homologues. The combined features of a calixarene-like macrocyclic scaffold and the presence of multiple selenium atoms create appealing (biomimetic) supramolecular opportunities.
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