期刊
ORGANIC LETTERS
卷 11, 期 13, 页码 2908-2911出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol900947d
关键词
-
资金
- Natural Science Foundation of China [20872126]
- Zhejiang Provincial Natural Science Foundation of China [R407106]
A novel difunctionalization reaction of vinylarenes with cyclic ethers has been developed by copper catalysis via direct activation of alpha-sp(3) C-H bonds of oxygen in the presence of 1-1.2 equiv of TBHP under mild aerobic conditions. The reaction shows excellent regioselectivities and good functional group tolerance to give the oxyalkylated products of vinylarenes.
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