期刊
ORGANIC LETTERS
卷 11, 期 3, 页码 769-772出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol8028302
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资金
- University of Alabama
The enantioselective formal synthesis of the polyketide marine natural Product (-)-clavosolide A is presented. The construction of the beta-C-glycoside subunit is highlighted by a one-pot oxocarbenium cation formation/reduction sequence. Yamaguchi dimerization afforded the diolide aglycon in 18 steps (longest linear sequence).
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