期刊
ORGANIC LETTERS
卷 11, 期 12, 页码 2595-2598出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol900920p
关键词
-
资金
- Fonds der Chemische Industrie
- graduate program Nanomolecular Science Jacobs University
The rates of acid hydrolysis of N-benzoyl-cadaverine (1), mono-N(tert-butoxy)carbonyl cadaverine (2), and benzaldoxime (3) with binding motifs for cucurbit[6]uril (1,2) and cucurbit[7]uril (1,3) were investigated in the absence and presence of these hosts. Significant rate enhancements (up to a factor of ca. 300 for the hydrolysis of 3) were observed. Competitive inhibition due to encapsulation of added cadaverine and the successful use of sub-stoichiometric amounts of macrocycle confirmed the function of cucurbiturils in promoting acid hydrolysis.
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