期刊
ORGANIC LETTERS
卷 11, 期 7, 页码 1627-1630出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol9003433
关键词
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资金
- National Science foundation [CHE-0704015]
- NSF CRIPMU award to the University of New Mexico [CHE-0443580]
An unprecedented highly enantioselective cascade oxa-Michael-Michael reaction has been developed. The simple and practical process, efficiently catalyzed by chiral diphenylprolinol TMS ether, affords a powerful access to highly functionalized synthetically useful chiral chromans. Moreover, notably a new activation mode involving an aminal is disclosed for the first time.
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