期刊
ORGANIC LETTERS
卷 11, 期 1, 页码 17-20出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol8022193
关键词
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资金
- Korea Science and Engineering Foundation (KOSEF)
- MarineBio Technology Program funded by Ministry of Land, Transport, and Maritime Affairs (MLTM), Korea
- Ministry of Education, Science & Technology (MEST)
We developed a novel regioselective synthesis of tetrasubstituted pyrroles via the classic 1,3-dipolar cycloaddition of alpha,beta-unsaturated benzofuran-3(2h)-one and azlactones (1) followed by spontaneous decarboxylation. The complete regiochemical control of tetrasubstituted pyrroles was confirmed by the orthogonal synthesis of complementary regioisomers (7a and 7b) simply by using different azlactones (1a and 1b, respectively).
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