期刊
ORGANIC LETTERS
卷 11, 期 19, 页码 4286-4288出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol9016436
关键词
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资金
- JSPS
- Uehara Memorial Foundation
- Grants-in-Aid for Scientific Research [21590018] Funding Source: KAKEN
The catalytic oxidative desymmetrization of meso-diols was realized using a chiral iridium catalyst. In particular, the reaction is effective for the cyclic diols to give the corresponding hydroxy ketones in high chemical yields with high ee's. With this reaction as a key step, a short-step synthesis of common intermediate of ottelione and scyphostatin was achieved.
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