期刊
ORGANIC LETTERS
卷 11, 期 8, 页码 1829-1831出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol900441f
关键词
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资金
- Japan Society for the Promotion of Science [17390002]
- Ministry of Education, Culture, Sports, Science, and Technology, Japan [19790005]
- Uehara Memorial Fundation for the Promotion of Life Science
- Grants-in-Aid for Scientific Research [19790005, 21390001, 17390002] Funding Source: KAKEN
A highly enantioselective organocatalytic oxidative kinetic resolution (OKR) of racemic secondary alcohols has been accomplished using asymmetric organocatalysis. A panel of chirally modified 2-azaadamantane N-oxyls (AZADOs) exhibit superior catalytic activity and high enantioselectivity, allowing us to obtain optically active secondary alcohols with a k(rel) value up to 82.2.
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