期刊
ORGANIC LETTERS
卷 11, 期 3, 页码 641-644出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol802733t
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资金
- Ministerio de Educacion y Ciencia [CTQ2006-06741/BQU, CTQ2007-61462]
- Ramon y Cajal contract
The first general approach for the diastereoselective formation of a variety of optically pure anti-beta-fluoroalkyl beta-amino acid derivatives is described. The process relies on the stereocontrolled reaction, mediated by a remote sulfoxide, of fluorinated imines with sulfinylated benzyl carbanions, which are used as synthetic equivalents of chiral ester enolates.
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