期刊
ORGANIC LETTERS
卷 11, 期 17, 页码 3846-3849出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol9014255
关键词
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资金
- French Government, CNRS [PAI 0379XM]
- University of Nice-Sophia Antipolis
- France-Canada Funds
- French Ambassy in Canada
One of the shortest and most efficient routes toward a series of functionalized pentahelicenes is reported. Benzylic (dibromo)methine coupling is an important entry into functional helicene chemistry. It allowed a mono- or a double functionalization by some metal-catalyzed Ar-C, Ar-S, Ar-CN, and Ar-l bond formations. Those functions offer new avenues for further applications. For instance, helicene (4) can be supported on a Ag(001) surface, which was characterized by high-resolution NC-AFM imaging.
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