期刊
ORGANIC LETTERS
卷 11, 期 15, 页码 3338-3341出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol901194m
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资金
- Asahi Glass Foundation
The copper-promoted Huisgen reaction of alpha-ethynylphosphole P-oxides with aryl azides affords alpha-(1-aryl-1,2,3-triazol-4-yl)phospholes in high yield. The alpha-(1-phenyl-1,2,3-triazol-4-yl)phosphole exhibits different coordination behavior in the complexation with MCl(2)(cod) (M = Pd, Pt). It has been revealed that P,N-coordination to PdCl(2) dramatically changes the optical properties of the newly constructed phosphole-triazole hybrid pi-system.
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