期刊
ORGANIC LETTERS
卷 11, 期 11, 页码 2245-2248出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol900533h
关键词
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资金
- Ministry of Education, Culture, Sports, Science and Technology,Japan [19028009]
- Grants-in-Aid for Scientific Research [19028009] Funding Source: KAKEN
Optically active dinuclear palladium complexes containing a Pd-Pd bond were prepared by using (R,R)-bis(tert-butylmethylphosphino)methane ((R,R),t-Bu-MiniPHOS). The dinuclear palladium complexes coupled with silver triflate exhibited good to excellent enantioselectivities up to 99% in palladium-catalyzed alkylative ring-opening reactions of azabenzonorbornadienes.
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