4.8 Article

An Unprecedented Oxidative Wagner-Meerwein Transposition

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ORGANIC LETTERS
卷 11, 期 20, 页码 4756-4759

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AMER CHEMICAL SOC
DOI: 10.1021/ol902000j

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  1. Donors of the American Chemical Society Petroleum Research Fund
  2. Natural Sciences and Engineering Research Council of Canada (NSERC)
  3. Canada Foundation for Innovation (CFI)
  4. Quebec (FQRNT)
  5. Boehringer Ingelheim (Canada) Ltd

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An oxidative Wagner-Meerwein transposition involving different functionalities mediated by a hypervalent Iodine reagent has been accomplished. The strategy fits within the concept of aromatic ring umpolung and allows rapid access to highly functionalized cores.

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