期刊
ORGANIC LETTERS
卷 11, 期 12, 页码 2647-2649出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol900669t
关键词
-
资金
- American Chemical Society Petroleum Research Fund
- U.S. Department of Energy
- Robert H. Cole Foundation
Alkoxide C-O bond cleavage occurs readily at room temperature in the presence of titanium(IV) halide. Capture of the resultant carbocation by alkynes provides an efficient route to trisubstituted (E)-alkenyl halides with high stereoselectivity.
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