期刊
ORGANIC LETTERS
卷 11, 期 16, 页码 3550-3553出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol9012487
关键词
-
资金
- German Science Foundation
- Marie Curie SolarNType [MRTN-CT-2006-035533]
Novel boron-nitrogen-containing pi-conjugated compounds 3,3'- and 4,4'-((2,4,6-triisopropylphenyl)borylene)bis(N,N-diarylbenzenamine) (1-2), m- and p-phenylene bridged to the boron center, respectively, have been synthesized and characterized. Optical studies by means of UV-vis absorption and emission measurements as well as DFT calculations reveal a different charge transfer behavior between the para series and the meta series at ground and excited states.
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