期刊
ORGANIC LETTERS
卷 11, 期 2, 页码 393-396出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol802664m
关键词
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资金
- Ministerio de Ciencia e Innovacion [CTQ2006-01121]
- UAM-Consejeria de Educacion de la Comunidad de Madrid [CCG07-UAM/PPQ-1799]
- MICINN
alpha,beta-Unsaturated ketones are no longer the missing dipolarophiles in catalytic asymmetric 1,3-dipolar cycloaddition of azomethine ylides. In the presence of Cu-1-Fesulphos complexes as catalysts (5 mol %), these substrates combine high reactivity, wide substitution tolerance, moderate to good endo/exo selectivities, and high enantiocontrol. The endo/exo-diastereoselectivity of the reaction is strongly dependent on the cis or trans nature of the enone moiety.
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