期刊
ORGANIC LETTERS
卷 11, 期 9, 页码 1943-1946出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol900376r
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资金
- NSFC
- Chinese Academy of Sciences
- State Key Basic Research Program
The nucleophilic addition of cyanide to the trifluoroacetylamino group in 2 yields an amphiphilic species which would induce the aggregation of silole 1, and as a result, the fluorescence of the ensemble increases largely. Accordingly, a fluorescence turn-on detection of cyanide in aqueous solution can be established with the ensemble of silole 1 and compound 2. Also, this ensemble displays good selectivity toward cyanide over other common inorganic anions.
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