期刊
ORGANIC LETTERS
卷 11, 期 7, 页码 1539-1542出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol900194v
关键词
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资金
- British Columbia
- Canada Research Chair Program
- NSERC
- CIHR
- CFI
- MerckFrosst Canada
Iodobenzene diacetate in MeOH containing a catalytic amount of TFA efficiently oxidizes aldoximes to nitrile oxides. The latter may be trapped in situ with olefins in a bimolecular or an intramolecular mode. The new method enables the execution of tandem oxidative dearomatization of phenols/intramolecular nitrile oxide cycloaddition sequences leading to useful synthetic intermediates.
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