期刊
ORGANIC LETTERS
卷 11, 期 8, 页码 1677-1680出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol802882k
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资金
- CDTI (Spanish Ministry of Research and Science)
N-Methylanilines are readily synthesized in high yields through the copper(II)-promoted coupling of anilines and methylboronic acid. This method represents a new approach for the selective monomethylation of anilines, and it is the first reported example of a Chan-Lam coupling involving the use of methylboronic acid. An incubation period of the substrate with the copper reagent is needed before addition of the methylboronic acid.
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