期刊
ORGANIC LETTERS
卷 11, 期 16, 页码 3754-3756出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol901348f
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资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan [19105002]
- Kyoto University
- Sumitomo Foundation
A new synthetic method of spirooxindole derivatives has been developed by way of a palladium-catalyzed decarboxylative cyclization of gamma-methylidene-delta-valerolactones with isatins. By employing a newly prepared phosphoramidite ligand, the reaction proceeds smoothly with excellent diastereoselectivity. Preliminary results of its application to asymmetric catalysis using a chiral phosphoramidite ligand are also described.
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