期刊
ORGANIC LETTERS
卷 10, 期 21, 页码 5047-5050出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol802254z
关键词
-
资金
- University of Notre Dame
- College of Science Summer Under-graduate Research Fellowship (SURF) Program
A concise total synthesis of neopeltolide macrolactone has been accomplished in 14 steps in the longest linear sequence, 15 steps overall from commercially available materials. The present synthesis was highlighted by successful exploitation of ether transfer methodology and a radical cyclization reaction to directly establish the requisite stereochemistry of the tetrahydropyran core.
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