期刊
ORGANIC LETTERS
卷 10, 期 15, 页码 3367-3370出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol801227f
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资金
- NCRR NIH HHS [RR 04648] Funding Source: Medline
The identity of the ortho-substituent of an aryl azide influences its reactivity toward transition metals. Substitution of a vinyl group with an imine disables rhodium(II)-mediated C-H amination and triggers a Lewis acid mechanism catalyzed by iron(II) bromide to facilitate benzimidazole formation.
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