期刊
ORGANIC LETTERS
卷 10, 期 19, 页码 4243-4246出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol801644f
关键词
-
资金
- the Deutsche Forschungsgemeinschaft
- the Funds der Chemischen Industrie
- the Deutscher Akademischer Austausch Dienst
- the Alfried Krupp von Bohlen and Halbach Foundation
A large range of benzoins was successfully applied as C-nucleophiles in the palladium-catalyzed allylic alkylation with several allyl acetates, resulting in functionalized tertiary homoallylic alcohols. A number of unsymmetrical benzoins can be coupled with high levels of regio- and chemoselectivity. Finally, the challenging compatibility of free N-heterocyclic carbenes with a palladium catalyst has been utilized in a number of metal- and organocatalyzed three-component coupling reactions.
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